May 19, 2024
University of Maragheh
فارسی
Bagher Eftekhari-Sis

Bagher Eftekhari-Sis

Academic rank: Professor
Address: Department of Chemistry, University of Maragheh, P.O.Box 55181-83111, Maragheh, Iran
Education: PhD. in Organic Chemistry
Phone: +984137278900-Int.512
Faculty: Faculty of Basic Sciences
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Research

Title
Oxoperoxo tungsten(VI) complex immobilized on Schiff base-modified Fe3O4 magnetic nanoparticles as a heterogeneous catalyst for oxidation of alcohols with hydrogen peroxide
Type Article
Keywords
Tungsten(VI) complex; oxoperoxo; Schiff base; Fe3O4; magnetic nanoparticles; oxidation; benzyl alcohol
Year
2016
Journal JOURNAL OF COORDINATION CHEMISTRY
DOI 10.1080/00958972.2016.1251588
Researchers Bagher Eftekhari-Sis، Masoud Akbari، Mojtaba Amini، Fatemeh Ashouri،

Abstract

Oxoperoxo tungsten(VI) complex immobilized on Schiff base-modified Fe3O4 super paramagnetic nanoparticles were synthesized and appropriately characterized using FT-IR, XRD, SEM, TEM, EDX, BET, and VSM analysis. The synthesized nanoparticles efficiently catalyzed oxidation of benzylic alcohols with H2O2 as oxidant in high yields, with high to excellent selectivity. The catalyst can be recovered using an external magnetic field and recycled for subsequent oxidation reactions without any appreciable loss of efficiency. The simple preparation, high activity, excellent selectivity, and simple recoverability of the catalyst are advantageous.
University of Maragheh
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