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Ghodrat Mahmoudi

Ghodrat Mahmoudi

Academic rank: Associate Professor
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Education: PhD.
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Research

Title
Cyanosilylation of aldehydes catalyzed by mixed ligand copper(II) complexes
Type
JournalPaper
Keywords
Arylhydrazones of acetoacetanilide Mixed ligand CuIIcomplexes Cyanosilylation reaction of aldehydes with trimethylsilyl cyanide
Year
2018
Journal INORGANICA CHIMICA ACTA
DOI
Researchers Atash V. Gurbanov, ، Ghodrat Mahmoudi ، Fátima C. Guedes da Silva ، Fedor I. Zubkov ، Kamran T. Mahmudov ، Armando J.L. Pombeiro

Abstract

The new mixed ligand copper(II) complexes [Cu(HL)(H2O)(A)]·2H2O (1, NaH2L = sodium (Z)-2-(2-(1,3-dioxo-1-(phenylamino)butan-2-ylidene)hydrazinyl)benzenesulfonate, A = dimethylsulfoxide, [Cu(HL)(H2O)(B)] (2, B = 1,3,4-thiadiazol-2-amine), [Cu(HL)(H2O)(Y)]·1/2CH3OH (3, C = hexamethylenetetramine) and [Cu(HR)2(H2O)2](H2L)2 (4, HR = methyl picolinimidate derived from 2-cyanopyridine) were synthesized and characterized by IR and ESI-MS spectroscopies, elemental and X-ray crystal structural analyses. These compounds act as homogenous catalysts for the cyanosilylation reaction of a variety of both aromatic and aliphatic aldehydes with trimethylsilyl cyanide affording the corresponding cyanohydrin trimethylsilyl ethers in high yields (up to 85–99 %) in methanol and at room temperature.