2D and 3D Zn(II) coordination polymers based on 4′-(Thiophen-2-yl)-4,2′:6′,4′'-terpyridine: Structures and features of sorption behavior

Research

Title	2D and 3D Zn(II) coordination polymers based on 4′-(Thiophen-2-yl)-4,2′:6′,4′'-terpyridine: Structures and features of sorption behavior
Type	JournalPaper
Keywords	Metal-organic frameworksPolypyridylsN-donor ligandsIodine absorption
Year	2022
Journal	Journal of Molecular Structure
DOI
Researchers	Alexander S. Zaguzin ، Ghodrat Mahmoudi ، Taisia S. Sukhikh ، Ilyas F Sakhapov ، Dmitry A. Zherebtsov ، Fedor I. Zubkov ، Karina S. Valchuk ، Maxim N. Sokolov ، Vladimir P. Fedin ، Sergey A. Adonin

Abstract

Reactions of Zn(II) nitrate, 4′-(Thiophen-2-yl)-4,2′:6′,4′'-terpyridine (ThioTerPy) and terephtalic (bdc) or 2-iodoterephtalic (2-I-bdc) acids result in 2D coordination polymer [Zn2bdc(ThioTerPy)2(OH)2] (1) or 3D metal-organic framework [Zn(2-I-bdc)(ThioTerPy)] (2), respectively. Both compounds were characterized by X-ray diffractometry. For 2, I2 absorption, as well as selectivity of sorption of different organic substrates from mixtures was studied.

Ghodrat Mahmoudi

Research

Abstract