02 خرداد 1403
مهدي اسرافيلي ديزجي

مهدی اسرافیلی دیزجی

مرتبه علمی: استاد
نشانی:
تحصیلات: دکترای تخصصی / شیمی فیزیک-شیمی کوانتمی
تلفن:
دانشکده: دانشکده علوم پایه

مشخصات پژوهش

عنوان
Optimized adsorption of volatile organic compounds on the activated carbon prepared from mesquite grain: A combined experimental and computational study
نوع پژوهش مقاله چاپ شده
کلیدواژه‌ها
Activated carbon Adsorption Volatile organic compounds Kinetic study Mesquite grain
سال
2022
مجله Journal of Environmental Chemical Engineering
شناسه DOI
پژوهشگران سهیلا شرفی نیا ، علیمراد رشیدی ، مهدی اسرافیلی دیزجی

چکیده

In this research work, adsorption of VOC (here gasoline vapor) onto synthesized activated carbon (AC) from mesquite grain was investigated. AC was prepared using chemical activation method (with two-step, activation and paralyze) and phosphoric acid as activating agent. Also, the effect of important factors on the surface area and finally the adsorption capacity such as the phosphoric acid ratio to the raw material (RM), time and tem- perature of calcination were studied. Several techniques such as FT-IR, XRD, XPS, TPD, Boehm titration, BET, CHNs, SEM, and TGA/DTA, have been used to determine and confirm physicochemical surface variation during preparing and modifying the adsorbent. It was observed that activation by phosphoric acid at 600 ◦C and a 2 hr (i.e AC5:1.1–2–600) gives a surface area of 1452.4 m2/g. The AC5:1.1–2–600 displayed high adsorption capacity for VOC adsorption (642.86 mg.g