26 اردیبهشت 1403
رحمان كريمي نامي

رحمان کریمی نامی

مرتبه علمی: استادیار
نشانی:
تحصیلات: دکترای تخصصی / شیمی آلی
تلفن:
دانشکده: دانشکده علوم پایه

مشخصات پژوهش

عنوان
Application of Novel Magnetic Metal-Organic Frameworks (CuBDC-NH2) as a Catalyst for C-C Cross-Coupling Reactions
نوع پژوهش مقاله ارائه شده
کلیدواژه‌ها
CuBDC-NH2 MOF”, “Nanocatalyst”, “Magnetic”, “C-C coupling reactions
سال
2023
پژوهشگران رحمان کریمی نامی ، امیر سیدی سقزچی

چکیده

C-C coupling reactions represent a fundamental synthetic methodology widely employed in academic and industrial settings. Herein, we present a report on developing and synthesizing a heterogeneous catalyst that is environmentally compatible and has recycling capabilities. Furthermore, the utilization of this catalyst for C-C coupling reactions was explored [1-3]. In this regard, a novel magnetic metal-organic framework (MMOF) consisting of supported 1,10-phenanthroline-2,9-dicarbaldehyde (Fe3O4@Cu(BDC)-NH2-PHD) has been fabricated by post-synthetic modifications of Fe3O4@Cu(BDC)-NH2. Subsequently, the prepared nanocomposites were modified using palladium chloride ions (Fe3O4@Cu(BDC)-NH2-PdPHD) to impart catalytic sites. As a result, the fabricated magnetic porous catalyst exhibited great catalytic activity in the Heck cross-coupling reactions. The structure of this synthetic Nanocatalyst is fully characterized with different techniques, including FT-IR, XRD, SEM, EDS, VSM, and TGA analyses.