2025/12/5
Rahman Kariminami

Rahman Kariminami

Academic rank: Assistant Professor
ORCID:
Education: PhD.
H-Index:
Faculty: Faculty of Basic Sciences
ScholarId:
E-mail: r.kariminami [at] gmail.com
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Phone:
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Research

Title
Phosphorylation of 2-Aryl Quinoxaline Derivatives via C-H/P-H Cross Coupling under Transition-Metal- Free Conditions
Type
JournalPaper
Keywords
Phosphorus-substituted heterocycles; 2-Aryl quinoxalines; dialkyl phosphites; C-H activitaion
Year
2021
Journal POLYCYCLIC AROMATIC COMPOUNDS
DOI
Researchers Rahman Kariminami ، Mehdi Adib ، Forouzan Heydari ، Saeideh Rajai-Daryasarei ، Idris Karakaya

Abstract

In this study, we have developed an efficient protocol for synthesis of phosphorus-substituted heterocycles through reaction between 2-Aryl quinoxalines and dialkyl phosphites under transition-metal-free conditions. Here, K2S2O8 has been used as the sole oxidant for the facile synthesis of phosphorus substituted derivates. A variety of heteroaryl phosphonate derivatives have been synthesized under optimized conditions in good to excellent yields with this facile and environment friendly protocol.