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Rahman Kariminami

Rahman Kariminami

Academic rank: Assistant Professor
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Education: PhD.
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Faculty: Faculty of Basic Sciences
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Research

Title
Application of Novel Magnetic Metal-Organic Frameworks (CuBDC-NH2) as a Catalyst for C-C Cross-Coupling Reactions
Type
Presentation
Keywords
CuBDC-NH2 MOF”, “Nanocatalyst”, “Magnetic”, “C-C coupling reactions
Year
2023
Researchers Rahman Kariminami ، Amir Seyedi saghezchi

Abstract

C-C coupling reactions represent a fundamental synthetic methodology widely employed in academic and industrial settings. Herein, we present a report on developing and synthesizing a heterogeneous catalyst that is environmentally compatible and has recycling capabilities. Furthermore, the utilization of this catalyst for C-C coupling reactions was explored [1-3]. In this regard, a novel magnetic metal-organic framework (MMOF) consisting of supported 1,10-phenanthroline-2,9-dicarbaldehyde (Fe3O4@Cu(BDC)-NH2-PHD) has been fabricated by post-synthetic modifications of Fe3O4@Cu(BDC)-NH2. Subsequently, the prepared nanocomposites were modified using palladium chloride ions (Fe3O4@Cu(BDC)-NH2-PdPHD) to impart catalytic sites. As a result, the fabricated magnetic porous catalyst exhibited great catalytic activity in the Heck cross-coupling reactions. The structure of this synthetic Nanocatalyst is fully characterized with different techniques, including FT-IR, XRD, SEM, EDS, VSM, and TGA analyses.