2026/4/17
Siamak Zavareh

Siamak Zavareh

Academic rank: Associate Professor
ORCID:
Education: PhD.
H-Index:
Faculty: Faculty of Basic Sciences
ScholarId:
E-mail: ss.zavareh [at] gmail.com
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Research

Title
Efficient enhancement of impact strength of epoxy thermoset using Triton X-100
Type
JournalPaper
Keywords
Thermosetting polymers, impact strength, mechanical properties, thermal stability, non-ionic surfactant
Year
2025
Journal Journal of Reinforced Plastics and Composites
DOI
Researchers Siamak Zavareh ، Zahra Mahtabi

Abstract

In this study, Triton X-100, a commercially available non-ionic surfactant, was investigated as a novel toughening modifier for an epoxy-based thermoset. Incorporation of 8 phr Triton X-100 resulted in a remarkable 221% increase in impact strength compared to neat epoxy. SEM analysis revealed a nano-blend morphology with uniformly dispersed Triton X-100 nanoparticles (∼51 nm), while FTIR analysis confirmed interfacial chemical interactions between the modifier’s hydroxyl groups and the epoxy matrix. Mechanical testing showed that tensile strength and modulus decreased by 33% and 39%, respectively, while elongation at break increased by 191%, indicating enhanced ductility. Thermogravimetric analysis demonstrated that with increasing Triton X-100 content, the initiation degradation temperature (TID) decreased from 290°C to 219°C, whereas the maximum degradation temperature (Tmax) increased significantly from 372°C to 417°C, reflecting improved thermal stability at elevated temperatures. Chemical resistance remained largely unchanged, except for a moderate reduction in stability against sulfuric acid. Overall, the findings highlight Triton X-100 as a promising and industrially viable toughening agent for epoxy thermosets, offering a favorable balance of mechanical and thermal performance for advanced structural applications.