|
Title
|
X-RAY CRYSTAL STRUCTURES, HIRSHFELD SURFACE ANALYSIS, AND DFT CALCULATIONS ON Hg(II) COMPLEXES: EXPLORING THE EFFECT OF WEAK INTERACTION ON THE FINAL STRUCTURE
|
|
Type
|
Presentation
|
|
Keywords
|
Schiff basesو novel mercury complex,isonicotinoyl hydrazone
|
|
Abstract
|
Schiff bases are important systems in asymmetric catalysis [1] and their transition metal complexes can often mimic biological sites; they are therefore of great interest as enzyme models [2]. When growing crystals from solution, the solvent used sometimes plays a role in determining the crystal structure that is obtained [3]. This role can range from influencing the polymorph that is grown to being built in into the crystal structure itself to form a solvate. In this study, we synthesized a novel mercury complex using Schiff base namely 2- pyridinecarbaldehyde isonicotinoyl hydrazone (HL), described the IR, X-ray crystal structures of this compounds.
|
|
Researchers
|
Fedor I. Zubkov (Third Researcher), Atash V. Gurbanov, (Second Researcher), Ghodrat Mahmoudi (First Researcher)
|