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Title
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Thiourea bridged periodic mesoporous organosilica with ultra-small Pd nanoparticles for coupling reactions
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Type
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JournalPaper
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Keywords
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periodic mesoporous organosilica ; Thiourea bridged PMO
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Abstract
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A synthesis of thiourea-bridged mesoporous organosilica is reported. Using transmission electron microscopy, low-angle XRD measurements and N2 adsorption–desorption isotherms the formation of a highly ordered mesoporous structure with a high surface area (>400 m2 g1) has been confirmed. Deposition of Pd nanoparticles inside the mesopores resulted in a material that showed excellent catalytic activity in a Suzuki-coupling reaction and retained this activity over several consecutive runs.
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Researchers
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Yusuke Yamauchi (Not In First Six Researchers), Behzad Zeynizadeh (Not In First Six Researchers), Nao Tsunoji (Not In First Six Researchers), Jungmok You (Not In First Six Researchers), Christopher Hyland (Not In First Six Researchers), Shiva Mohammadi (Fifth Researcher), Yusuke Ide (Fourth Researcher), Masataka Imura (Third Researcher), Sadegh Rostamnia (Second Researcher), (First Researcher)
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