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Title
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Nanoarchitecturing of open metal site Cr-MOFs for oxodiperoxo molybdenum complexes [MoO(O2)2@En/MIL-100(Cr)] as promising and bifunctional catalyst for selective thioether oxidation
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Type
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JournalPaper
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Keywords
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Metal-organic framework Open metal site MOF Oxodiperoxo molybdenum complexes MoO(O2)2@En/MIL-100(Cr) Thioether oxidation
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Abstract
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In this work, open metal site metal-organic framework of MIL-100(Cr) was selected as a support for the multi-step grafting of molybdenum complexes. The oxodiperoxo molybdenum complexes were coordinated onto the ethylene diamine-decorated MIL-100(Cr) pore cage, that this bifunctional MoO(O2)2@En/MIL-100(Cr) catalyst was successfully applied for H2O2 (30%) mediate green and selective thioether oxidation process. Component activity and recyclability test for the MoO(O2)2@En/MIL-100(Cr) catalyst showed a successful reusability for 8 runs.
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Researchers
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Farahnaz Mohsenzad Farahnaz Mohsenzad (Second Researcher), Sadegh Rostamnia (First Researcher)
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