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Title
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Polymeric hybrid mesoporous silica hollow nanospheres as a support for palladium and application of the PdNPs@PANI/HNS nanocomposite for aerobic benzyl alcohol oxidation
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Type
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JournalPaper
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Keywords
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Hybrid mesoporous silica hollow nanospheres PdNPs/HSN Aerobic alcohol oxidation Transition metal
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Abstract
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The polyaniline composition by silica based mesoporous hollow nanosphere (silica-HNS) was synthesized and selected as a promising solid support for palladium nanoparticle stabilization. Then the nanocomposite was applied as a nanocatalyst for aerobic benzyl alcohol oxidation reactions. Catalyst recyclability showed six successful runs for the reaction. TEM and SEM-EDX/mapping images were used to study the structure and morphology of the PdNPs@PANI/HNS. FT-IR spectroscopy, Thermal gravimetric analysis (TGA), and BET were used to characterize and investigate the catalyst nature. In addition, the amounts of Pd loading were characterized by ICP-AES technique
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Researchers
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(Second Researcher), Sadegh Rostamnia (First Researcher)
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