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Abstract
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In the present study, open metal site iron-based MOF [MIL-100(Fe)], by a solvothermal method with polygonal morphology, are synthesised and then applied as a heterogeneous green catalyst for aza-Michael addition of various amines with α, β-unsaturated compounds. The MIL-100(Fe) was found to be efcient, selective, green and heterogeneous catalyst for the azaMichael reaction. The proposed catalyst has better recyclability and can be reused six times without apparent loss of activity.
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