Research Info

Home /Palladium Comprising ...
Title Palladium Comprising Dicationic Bipyridinium Supported Periodic Mesoporous Organosilica (PMO): Pd@Bipy–PMO as an Efficient Hybrid Catalyst for Suzuki–Miyaura Cross-Coupling Reaction in Water
Type JournalPaper
Keywords ionic liquid; heterogeneous catalyst; hybrid materials; mesoporous silica; Suzuki–Miyaura reaction
Abstract In this study, we developed a novel catalysts consisting of periodic mesoporous organosilica functionalized with bipyridinium ionic liquid supported palladium. The physiochemical properties of the hybrid catalyst were investigated using Fourier transform infrared spectroscopy, small angle X–ray powder diffraction, field emission scanning electron microscope, transmission electron microscope, nitrogen adsorption–desorption analyses, and atomic absorption spectroscopy. The stabilized Pd species inside the mesochannels provided good catalytic efficiency for the Suzuki–Miyaura coupling reactions in water. The activity of the designed catalysts retained for several consecutive recycle runs. The stability, recoverability, and reusability of the designed heterogeneous catalyst were also studied under various reaction conditions.
Researchers Mohammadreza Shokouhimehr (Not In First Six Researchers), Zengjian An (Not In First Six Researchers), Qingshan Kong (Fifth Researcher), Lee Wilson (Fourth Researcher), Paria Panahi (Third Researcher), Sadegh Rostamnia (Second Researcher), Arefeh Ahadi (First Researcher)