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Title
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CRYSTAL STRUCTURE OF (E)-N'-((1H-PYRROL-2-YL)METHYLENE)-4-HYDROXYBENZOHYDRAZIDE
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Type
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JournalPaper
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Keywords
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Hydrazide, X-ray diffracction, non-covalent interactions, Hirshfeld surface, energy framework
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Abstract
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The title compound corresponds to an enaminone E isomer in the solid state. X-ray structure shows that this crystallizes in the orthorrombic system, with space group Pna21 with 2 independent molecules in the asymmetric unit in a non-centrosymmetric setting. The CNNC unit forms dihedral angles of 5.9(3)/2.1(3); 19.7(3)/17.6(3)° with the pyrrole and phenol rings for molecules A and B respectively. The main differences between both molecules is the dihedral torsion between rings, their mean planes form dihedral angles of 25.45(15) and 15.38(15)° for the molecules A and B. In the asymmetric unit, molecules are linked by two weak N – H···O hydrogen bonds with set graph-motif
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Researchers
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Alejandro Cárdenas (Not In First Six Researchers), Jonathan Cisterna (Fifth Researcher), Iván Brito (Fourth Researcher), Guillermo Zaragoza (Third Researcher), Sadegh Rostamnia (Second Researcher), Ghodrat Mahmoudi (First Researcher)
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