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Title
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Unmodified SBA-15 adsorbents for the removal and separation of Th(IV) and U(VI) ions: the role of pore channels and surface-active sites
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Type
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JournalPaper
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Keywords
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Adsorption; unmodified SBA-15; pores; surface; thorium(IV); uranium(VI)
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Abstract
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The removal of Th(IV) and U(VI) by calcinated, non-calcinated, and methyl grafted SBA-15 (abbreviated as SBA-15, SBA-15-NC and SBA-15-MG, correspondingly) were compared to elucidate the role of pores and surface adsorption sites on SBA-15 adsorbents. It was proposed that the contribution of pores and surface-active sites of SBA-15 increases its higher adsorption capacity with respect to the other examined adsorbents. The kinetic studies revealed that the adsorption and also desorption occurred initially on the surface and then to the pores. Adsorption/desorption of the ions into pores was occurred with slow kinetics.
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Researchers
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Sadegh Rostamnia (Fourth Researcher), Mohammad Reza Yaftian (Third Researcher), Mehri Shateri (Second Researcher), Leila Dolatyari (First Researcher)
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