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Title
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A novel binuclear iron(III)-salicylaldazine complex; synthesis, X-ray structure and catalytic activity in sulfide oxidation
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Type
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JournalPaper
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Keywords
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Catalyst Binuclear Iron Oxidation Sulfide
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Abstract
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A novel binuclear iron(III)-salicylaldazine complex has been synthesized and characterized by various techniques such as IR and UV–Vis spectroscopy and X-ray crystallography. The catalytic oxidation of sulfides in the presence of the aforementioned complex was explored at room temperature using urea hydrogen peroxide (UHP) as an oxidant. Effects of different reaction conditions consisting catalyst and oxidant amount, solvent effect and reaction time on the catalytic activity and selectivity in the reaction of methylphenylsulfide oxidation has been surveyed. Perfect selectivity toward sulfoxide was achieved after 15 min in CH3CN by choice of a properly optimized reaction condition.
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Researchers
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Mojtaba Amini (Third Researcher), (Not In First Six Researchers), Arkady Ellern (Fifth Researcher), Ali Akbari (Fourth Researcher), (Second Researcher), Elnaz Mesbahi (First Researcher)
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