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Title
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Selective oxidation of organosulfurs with a sandwich-type polyoxometalate/hydrogen peroxide system
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Type
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JournalPaper
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Keywords
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Sandwich-type POM Nanocluster Selective oxidation Sulfide
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Abstract
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A dimeric tungstophosphate, Na14[Co4(PW9O35)2].28H2O (1), was synthesized via a simple one-pot method and characterized by single-crystal X-ray crystallography. Nanocluster 1 was exhibited to be able to selective oxidation of aliphatic and aromatic sulfides to sulfoxides in the presence of hydrogen peroxide at room temperature with high performance. Further investigations showed that this catalyst could reuse four times without a significant reduction in its activity for the oxidation of methyl phenyl sulfide.
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Researchers
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Jan Janczak (Not In First Six Researchers), (Not In First Six Researchers), (Fifth Researcher), Arshad Bayrami (Fourth Researcher), Mohammad Amin Dastyar (Third Researcher), Mojtaba Amini (Second Researcher), (First Researcher)
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