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Title
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Porous triazine polymer: A novel catalyst for the threecomponent reaction
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Type
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JournalPaper
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Keywords
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A 3 -coupling reaction, au-NCs@Triazine-COPs, covalent organic polymers (COPs), gold nanocluster
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Abstract
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A new porous triazine-based covalent organic polymer (Triazine-COP) was prepared through the Schiff-base condensation of 2,4,6-tris(4-formyl phenoxy)-1,3,5-triazine and 4,4 0 -oxydianiline, under sonication. The synthesized Triazine-COP with a high surface area was stable in water and other organic solvents. In the next step, Au (III) ions were immobilized on the nitrogen-rich Triazine-COP that on the reduction with NaBH4produced the heterogeneous catalyst of gold clusters in nanosize (Au-NCs@Triazine-COPs). It was applied as an efficient catalyst for the A 3 coupling reaction of alkynes, aldehydes with and amines. Both electron-withdrawing/releasing groups produced the corresponding propargylamines with high yields. The high activity of the Au-NCs@Triazine-COPs in this reaction was because of the nanoporous structure of the support that enables the high dispersion and an unhindered open environment for the NCs. The catalyst was reused up to 7 times without significant loss in activity.
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Researchers
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Rana Boluki (Not In First Six Researchers), Samad Khaksar (Not In First Six Researchers), Sadegh Rostamnia (Fifth Researcher), Behnam Gholipour (Fourth Researcher), Nazanin Mokhtari (Third Researcher), Mohammad Dinari (Second Researcher), (First Researcher)
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