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Title
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Catalytic oxidation of organic sulfides by new iron-chloro Schiff base complexes: The effect of methoxy substitution and ligand isomerism on the electronic, electrochemical and catalytic performance of the complexes
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Type
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JournalPaper
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Keywords
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Catalysis Iron-chloro Schiff base Sulfoxidation
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Abstract
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Four new Fe(III)-Chloro Schiff base complexes were synthesized and characterized. The N2O2 type tetradentate Schiff base ligands were synthesized from the condensation of meso-1,2-diphenyl-1,2- ethylenediamine with salicylaldehyde (H2L1), 3-methoxysalicylaldehyde (H2L2), 4-methoxysalicylaldehyde (H2L3) and 5-methoxysalicylaldehyde (H2L4). The corresponding iron-chloro complexes with the general formula [Fe(Ln)Cl] (n = 1–4 for complexes (1–4)) were characterized by FTIR and UV–Vis spectroscopy and elemental analysis. Crystal structure of (1) was obtained by single-crystal X-ray crystallography. Cyclic voltammetry was used to study the electrochemistry of the complexes. The complexes were used as catalysts for the selective oxidation of organic sulfide compounds to sulfoxides. High catalytic performance and selectivity were obtained. The spectroscopic, electrochemical and catalytic data are discussed based on the electronic, steric and electrochemical properties of the complexes.
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Researchers
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(Not In First Six Researchers), Mojtaba Amini (Not In First Six Researchers), Rahman Kariminami (Fifth Researcher), Michal Dusek (Fourth Researcher), Monika Kucerakova (Third Researcher), (Second Researcher), (First Researcher)
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