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Title 2D and 3D Zn(II) coordination polymers based on 4′-(Thiophen-2-yl)-4,2′:6′,4′'-terpyridine: Structures and features of sorption behavior
Type JournalPaper
Keywords Metal-organic frameworksPolypyridylsN-donor ligandsIodine absorption
Abstract Reactions of Zn(II) nitrate, 4′-(Thiophen-2-yl)-4,2′:6′,4′'-terpyridine (ThioTerPy) and terephtalic (bdc) or 2-iodoterephtalic (2-I-bdc) acids result in 2D coordination polymer [Zn2bdc(ThioTerPy)2(OH)2] (1) or 3D metal-organic framework [Zn(2-I-bdc)(ThioTerPy)] (2), respectively. Both compounds were characterized by X-ray diffractometry. For 2, I2 absorption, as well as selectivity of sorption of different organic substrates from mixtures was studied.
Researchers Sergey A. Adonin (Not In First Six Researchers), Vladimir P. Fedin (Not In First Six Researchers), Maxim N. Sokolov (Not In First Six Researchers), Karina S. Valchuk (Not In First Six Researchers), Fedor I. Zubkov (Not In First Six Researchers), Dmitry A. Zherebtsov (Fifth Researcher), Ilyas F Sakhapov (Fourth Researcher), Taisia S. Sukhikh (Third Researcher), Ghodrat Mahmoudi (Second Researcher), Alexander S. Zaguzin (First Researcher)