|
Title
|
Pd(PrSO3)2@SBA-15 and Pd-NPs(PrSO3)@SBA-15 hybrid materials: A highly active, reusable, and selective interface catalyst for C–X activations in air and water
|
|
Type
|
JournalPaper
|
|
Keywords
|
Pd(PrSO3)2@SBA-15; Pd-NPs(PrSO3)@SBA-15; Interface catalyst; Suzuki C–X activations.
|
|
Abstract
|
A series of ordered mesoporous organic–inorganic hybrid material are designed by using the SO3H-functionalized SBA-15 [(PdX2@SBA-15/SO3H or Pd(PrSO3)2@SBA-15) and (Pd-NPs@SBA-15/SO3H or Pd-NPs(PrSO3)@SBA-15)] as solid supports for palladium ions. Among them, the encapsulated Pd(MeCN)2Cl2 into the SBA-15/SO3H and Pd-NPs@SBA-15/SO3H exhibit higher activity and selectivity toward Suzuki cross-coupling reaction in aerobic condition and water/DMF solvent. These heterogeneous palladium precatalysts could be separated from the reaction mixture and reused at least 11 times.
|
|
Researchers
|
Hongchuan Xin (Third Researcher), Turaj Rahmani (Second Researcher), Sadegh Rostamnia (First Researcher)
|