عنوان مجله
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JOURNAL OF ORGANOMETALLIC CHEMISTRY
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چکیده
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In this work, SBA-15 was selected as a support for the homoleptic chelating N-heterocyclic carbene
complexes of palladium. Here, Pd2þ ions were coordinated to N-heterocyclic carbene (NHCePd) which
also contain ionic liquid. Then, this NHCePd@SBA-15/IL catalyst (NHCePd active part of the catalyst) was
successfully applied in the catalysis of Hiyama coupling reaction with lower mol% Pd rather to previously
reported literatures. The role of TBAF and Cs2CO3 in the decrease of Pd mol% was crucial. Recyclability test
showed a successful reusability for 5 runs. Simultaneous application of TBAF and NaOH did destroy the
silica structure of SBA-15 in the first run.
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