عنوان مجله
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APPLIED ORGANOMETALLIC CHEMISTRY
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چکیده
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An efficient procedure based on arginine‐modified Fe3O4@carbon magnetic nanoparticles (FCA MNPs) with highly dispersed copper nanoparticles (Cu NPs) and
92.8 ppm of Pd is reported for room temperature Suzuki reaction. For enhancing
the activity of this Cu‐based heterogeneous catalyst, special arginine amino acid
as a ligand with high content of heteroatoms was immobilized onto the
Fe3O4@carbon MNPs to increase the electron density. Cu(II) ions were then loaded
on the surface of the FCA MNPs and reduced to achieve uniformly dispersed Cu
NPs. An aqueous mixture of metal hydroxides such as KOH, Ba(OH)2, Ca(OH)2,
Mg(OH)2 as a green, non‐toxic and basic medium was used for the Suzuki reaction
at room temperature. This catalyst could also be recovered and reused with no loss
of activity over six successful runs.
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