مشخصات پژوهش

صفحه نخست /Palladium Comprising ...
عنوان
Palladium Comprising Dicationic Bipyridinium Supported Periodic Mesoporous Organosilica (PMO): Pd@Bipy–PMO as an Efficient Hybrid Catalyst for Suzuki–Miyaura Cross-Coupling Reaction in Water
عنوان مجله Catalysts
نوع پژوهش مقاله چاپ شده
کلیدواژه‌ها
ionic liquid; heterogeneous catalyst; hybrid materials; mesoporous silica; Suzuki–Miyaura reaction
چکیده
In this study, we developed a novel catalysts consisting of periodic mesoporous organosilica functionalized with bipyridinium ionic liquid supported palladium. The physiochemical properties of the hybrid catalyst were investigated using Fourier transform infrared spectroscopy, small angle X–ray powder diffraction, field emission scanning electron microscope, transmission electron microscope, nitrogen adsorption–desorption analyses, and atomic absorption spectroscopy. The stabilized Pd species inside the mesochannels provided good catalytic efficiency for the Suzuki–Miyaura coupling reactions in water. The activity of the designed catalysts retained for several consecutive recycle runs. The stability, recoverability, and reusability of the designed heterogeneous catalyst were also studied under various reaction conditions.
پژوهشگران عارفهاحدی (نفر اول)، صادقرستم نیا (نفر دوم)، پریاپناهی (نفر سوم)، ویلسنلی (نفر چهارم)، کینگ شانکونگ (نفر پنجم)، ژنگ چینآن (نفر ششم به بعد)، محمد رضاشکوهی مهر (نفر ششم به بعد)