چکیده
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A novel binuclear iron(III)-salicylaldazine complex has been synthesized and characterized by various
techniques such as IR and UV–Vis spectroscopy and X-ray crystallography. The catalytic oxidation of sulfides
in the presence of the aforementioned complex was explored at room temperature using urea
hydrogen peroxide (UHP) as an oxidant. Effects of different reaction conditions consisting catalyst and
oxidant amount, solvent effect and reaction time on the catalytic activity and selectivity in the reaction
of methylphenylsulfide oxidation has been surveyed. Perfect selectivity toward sulfoxide was achieved
after 15 min in CH3CN by choice of a properly optimized reaction condition.
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