عنوان مجله
|
POLYCYCLIC AROMATIC COMPOUNDS
|
چکیده
|
An inside needle capillary adsorption trap based on polypyrrole/hexagonally ordered mesoporous silica was fabricated and used to extract
polycyclic aromatic hydrocarbons. Chemical polymerization was used for
synthesizing polypyrrole/hexagonally ordered mesoporous silica. Polypyrrole/
hexagonally ordered silica was analyzed by scanning electron microscopy
and thermo gravimetric methods. The prepared nanoporous material was
immobilized into a stainless steel needle to fabrication of the inside needle
capillary adsorption trap device. The inside needle capillary adsorption trap
device was applied for the extraction of some polycyclic aromatic hydrocarbons from aqueous samples in combination with gas chromatography-mass
spectrometry. A simplex method was used for optimization of factors affecting the extraction efficiency of the method. The detection limits of the
method under optimized conditions (extraction time of 15 min at 50 C,
sampling flow rate of 5 mLmin1
, NaCl 12% w/v) were in the range of
0.001–0.005 ngmL1
. The relative standard deviations at a concentration
level of 1 ngmL1 were between 3.2% and 10.1% (n¼ 4)
|