عنوان مجله
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POLYCYCLIC AROMATIC COMPOUNDS
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چکیده
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The present study explains the in situ growth of Cu cluster-based metalorganic framework on copper substrate for thin film microextraction
approach. Cu cluster-based metal-organic framework has been growth via
a hydrothermal method on electrochemically anodized copper substrate.
After thin film microextraction, some polycyclic aromatic hydrocarbons
were quantified via high performance liquid chromatography- photo diode
array detection. The influence of effective parameters such as extraction
time, extraction temperature, agitator speed and ionic strength of the sample was investigated and the optimum conditions were chosen. Calibration
curves were obtained in 0.0001–10 mgL1 range with acceptable linearity
as R2 > 0.986. The range of 1 and 3 pgL1 was calculated as limits of
detection, with the relative standard division below 5.1% in the optimal
condition. For evaluating the model, samples from river water and wastewater were used and investigated. It was found that relative recoveries
were between 96-104%. The proposed method provided a simple, efficient
and environmental approach for the rapid and convenient determination
of polycyclic aromatic hydrocarbons in real samples.
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