عنوان مجله
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POLYCYCLIC AROMATIC COMPOUNDS
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چکیده
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A porous magnetic multifunctional copper-based metal-organic framework
(MOF) was developed through combined covalent and dative post-synthetic
modification (PSM) of the CuBDC. In this regard, a novel magnetic
metal-organic framework (MMOF) consisting of supported 1,10-phenanthroline-
2,9-dicarbaldehyde (Fe3O4@Cu(BDC)-NH2-PHD) has been fabricated
by post-synthetic modifications of Fe3O4@Cu(BDC)-NH2. Subsequently, the
prepared nanocomposites were modified using palladium chloride ions
(Fe3O4@Cu(BDC)-NH2-PdPHD) to impart catalytic sites. As a result, the fabricated
magnetic porous catalyst exhibited great catalytic activity in Suzuki-
Miyaura cross-coupling reactions. Some of the essential advantages of the
synthesized catalyst are; high catalytic activity, short reaction times, mild
conditions, high thermal stability, and reusability. Moreover, his porous
magnetic nanomaterial can be used as a new support to immobilize other
metals in different catalytic reactions.
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