مشخصات پژوهش

صفحه نخست /Surfactant-Exfoliated Highly ...
عنوان
Surfactant-Exfoliated Highly Dispersive Pd-Supported Graphene Oxide Nanocomposite as a Catalyst for Aerobic Aqueous Oxidations of Alcohols
عنوان مجله ChemCatChem
نوع پژوهش مقاله چاپ شده
کلیدواژه‌ها
alcohols · graphene · palladium · supported catalysts · surfactants
چکیده
A pluronic P123 surfactant was employed in the exfoliation and stabilization of Pd0-supported graphene oxide (PdNPs–GO; NPs=nanoparticles) nanosheets in aqueous solution during the oxidation of benzylic and aliphatic alcohols under aerobic conditions at 80 °C. Surfactants prevented the aggregation of PdNPs–GO sheets at 80 °C under aqueous conditions and PdNPs–GO/P123 adducts acted as a highly dispersive homogeneous-like catalyst. The catalytic performance of the nanocomposite material was remarkably improved, being highly stable and reusable in the aerobic oxidation of alcohols for at least nine runs.
پژوهشگران صادقرستم نیا (نفر اول)، اسماعیلدوستخواه (نفر دوم)، زیباکریمی (نفر سوم)، ثریاامینی (نفر چهارم)، رافائللوکوئه (نفر پنجم)