مشخصات پژوهش

صفحه نخست /Oxoperoxo tungsten(VI) ...
عنوان Oxoperoxo tungsten(VI) complex immobilized on Schiff base-modified Fe3O4 magnetic nanoparticles as a heterogeneous catalyst for oxidation of alcohols with hydrogen peroxide
نوع پژوهش مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها Tungsten(VI) complex; oxoperoxo; Schiff base; Fe3O4; magnetic nanoparticles; oxidation; benzyl alcohol
چکیده Oxoperoxo tungsten(VI) complex immobilized on Schiff base-modified Fe3O4 super paramagnetic nanoparticles were synthesized and appropriately characterized using FT-IR, XRD, SEM, TEM, EDX, BET, and VSM analysis. The synthesized nanoparticles efficiently catalyzed oxidation of benzylic alcohols with H2O2 as oxidant in high yields, with high to excellent selectivity. The catalyst can be recovered using an external magnetic field and recycled for subsequent oxidation reactions without any appreciable loss of efficiency. The simple preparation, high activity, excellent selectivity, and simple recoverability of the catalyst are advantageous.
پژوهشگران مجتبی باقرزاده (نفر پنجم)، فاطمه آشوری (نفر چهارم)، مجتبی امینی (نفر سوم)، مسعود اکبری (نفر دوم)، باقر افتخاری سیس (نفر اول)