عنوان
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The determination of n-pentane solubility and diffusivity in styrene– methyl methacrylate copolymers via designed apparatus
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نوع پژوهش
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مقاله چاپشده در مجلات علمی
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کلیدواژهها
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Styrene–methyl methacrylate copolymer, solubility, diffusivity, n-pentane, suspension polymerization
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چکیده
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In this work, styrene–methyl methacrylate copolymer particles were synthesized by suspension polymerization process with different copolymer compositions. A system was designed to measure the solubility and diffusivity of n-pentane in the synthesized copolymers. The designed system consisted of the self-sealing cell equipped to the pressure and temperature controllers. The synthesized copolymer particles were impregnated by n-pentane and their expansion were recorded visually. Furthermore, the solubility and diffusivity of n-pentane in copolymer particles were measured by the same apparatus. The effect of different foaming conditions on the solubility and diffusivity of n-pentane in the samples were examined. It was concluded that the sorption pressure and temperature have contradictory effects on the solubility and diffusivity of n-pentane in styrene–methyl methacrylate copolymers at different sorption pressures. It was concluded that with methyl methacrylate content increment in copolymer, the diffusivity and dissolved n-pentane content in copolymer were reduced.
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پژوهشگران
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حمید رضا عظیمی زنوزی (نفر اول)، مصطفی رضایی (نفر دوم)
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