مشخصات پژوهش

عنوان	Zeolite-encapsulated tri-heteronuclear metal clusters as an efficient in the epoxidation of cyclohexane
نوع پژوهش	مقاله ارائه شده کنفرانسی
کلیدواژه‌ها	Epoxidation, Heterogeneous catalyst, Heteronuclear metal cluster, NaBr.
چکیده	Multinuclear active sites are similar to those of metalloenzymes and enzymes. Enzymes are polyfunctional catalysts containing several groups. Metal cluster complexes encapsulated within the nanopores of a zeolite are good mimics for metalloenzymes and proteins in biochemical transformations which catalyze consecutive chemical reactions. Here, we wish to report the synthesis of heteronuclear metal clusters [MM΄M̋ (O)(CH3COO)6-(py)3]-Y. this heterogeneous catalysts were characterized by Fourier transform infrared, Ultraviolet-visible, field scanning electron microscopy, X-ray diffraction and atomic absorption spectroscopy. The encapsulated metal clusters showed good catalytic activity in the epoxidation of cyclohexene with H2O2/O2. The epoxide yields were 70-90%. The effect of several parameters including temperature, oxidants and NaBr as an oxidation promoter was investigated
پژوهشگران	مریم موسوی فر (نفر اول)، سمیرا باقری (نفر دوم)، فریبا مودت (نفر سوم)، بهار پزشکی (نفر چهارم)