مشخصات پژوهش

صفحه نخست /Two new copper(II) complexes ...
عنوان Two new copper(II) complexes with chelating N,O-type bidentate ligands: Synthesis, characterization, crystal structure and catalytic activity in azide–alkyne cycloaddition reaction
نوع پژوهش مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها Copper Azide–alkyne cycloaddition 1,2,3-triazoles N,O-bidentate ligands
چکیده Tetra-coordinated copper(II) complexes, [CuL2] and [Cu(phox)2], were synthesized by reaction of 1-((4- bromophenylimino)methyl)naphthalen-2-ol, HL, and 2-(20-hydroxyphenyl)-2-oxazoline, Hphox, ligands with copper acetate, respectively. The complexes were characterized using FT-IR spectroscopy, elemental analyses, and their solid state structures were confirmed by single crystal X-ray diffraction. The catalytic activity of the complexes was evaluated in one-pot azide–alkyne cycloaddition (AAC) click reaction in water without need of any additional agent. The [CuL2] complex showed high catalytic activity in this reaction and 1,2,3-triazole derivatives were produced in moderate to good yields.
پژوهشگران پاول ر ریثبوی (نفر ششم به بعد)، لارنس ج کرشاو کوک (نفر پنجم)، مجتبی امینی (نفر چهارم)، رضا کیا (نفر سوم)، ارشد بایرامی (نفر دوم)، مجتبی باقرزاده (نفر اول)