مشخصات پژوهش

عنوان	A novel 12-molybdovanadate nanocluster: Synthesis, structure investigation and its application as an efficient heterogeneous sulfoxidation catalyst
نوع پژوهش	مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها	12-Molybdovanadate Nanocluster Sulfoxidation
چکیده	Tetraethylammonium salt of a new Keggin-type 12-molybdovanadate nanocluster, [(C2H5)4N]4[VMo12O40] (1) was synthesized via reaction between sodium tungstate, ammonium vanadate and tetraethylammonium bromide in acidic medium. Compound 1 was characterized by X-ray crystallography, FT-IR, UV–Vis and cyclic voltammetry and then applied as an efficient heterogeneous catalyst to oxidation of various organosulfides to sulfoxides with H2O2 at room temperature with 81–100% conversion and 60–99% selectivity. Nanocluster 1 was also shown to display excellent recyclability – it can be reused more than 10 times.
پژوهشگران	مالگورزاتا هولینسکا (نفر ششم به بعد)، مجتبی باقرزاده (نفر پنجم)، ارشد بایرامی (نفر چهارم)، هادی نسل حاجیان (نفر سوم)، آیدا شیخی (نفر دوم)، مجتبی امینی (نفر اول)