مشخصات پژوهش

عنوان	Nanoarchitecturing of open metal site Cr-MOFs for oxodiperoxo molybdenum complexes [MoO(O2)2@En/MIL-100(Cr)] as promising and bifunctional catalyst for selective thioether oxidation
نوع پژوهش	مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها	Metal-organic framework Open metal site MOF Oxodiperoxo molybdenum complexes MoO(O2)2@En/MIL-100(Cr) Thioether oxidation
چکیده	In this work, open metal site metal-organic framework of MIL-100(Cr) was selected as a support for the multi-step grafting of molybdenum complexes. The oxodiperoxo molybdenum complexes were coordinated onto the ethylene diamine-decorated MIL-100(Cr) pore cage, that this bifunctional MoO(O2)2@En/MIL-100(Cr) catalyst was successfully applied for H2O2 (30%) mediate green and selective thioether oxidation process. Component activity and recyclability test for the MoO(O2)2@En/MIL-100(Cr) catalyst showed a successful reusability for 8 runs.
پژوهشگران	صادق رستم نیا (نفر اول)، فرحناز محسن زاد (نفر دوم)