مشخصات پژوهش

عنوان	A highly sensitive electrochemical sensor for the determination of methanol based on PdNPs@SBA-15-PrEn modified electrode
نوع پژوهش	مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها	Methanol PdNPs@SBA-15-PrEn nanocomposite Electrochemical sensor
چکیده	In this study, a novel electrochemical sensor for the determination of methanol based on palladium nanoparticles supported on Santa barbara amorphous-15- PrNHEtNH2 (PdNPs@SBA-15-PrEn) as nanocatalysis platform is presented. Scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD) and electrochemical methods are employed to characterize the PdNPs@SBA-15-PrEn nanocomposite. The Nafion-Pd@SBA-15-PrEn modified glassy carbon electrode (Nafion-PdNPs@SBA-15-PrEn/GCE) displayed the high electrochemical activity and excellent catalytic characteristic for electro-oxidation of methanol in an alkaline solution. The electro-oxidation performance of the proposed sensor was investigated using cyclic voltammetry (CV) and amperometry. The sensor exhibits a good sensitivity of 0.0905 Amol−1 Lcm−2, linear range of 20–1000 μM and the corresponding detection limit of 12 μM (3σ). The results demonstrate that the Nafion-PdNPs@SBA-15-PrEn/GCE has potential as an efficient and integrated sensor for methanol detection.
پژوهشگران	صادق رستم نیا (نفر چهارم)، محمور عموزاده تبریزی (نفر سوم)، مجتبی شمسی پور (نفر دوم)، زیبا کریمی (نفر اول)