مشخصات پژوهش

صفحه نخست /Palladium Comprising ...
عنوان Palladium Comprising Dicationic Bipyridinium Supported Periodic Mesoporous Organosilica (PMO): Pd@Bipy–PMO as an Efficient Hybrid Catalyst for Suzuki–Miyaura Cross-Coupling Reaction in Water
نوع پژوهش مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها ionic liquid; heterogeneous catalyst; hybrid materials; mesoporous silica; Suzuki–Miyaura reaction
چکیده In this study, we developed a novel catalysts consisting of periodic mesoporous organosilica functionalized with bipyridinium ionic liquid supported palladium. The physiochemical properties of the hybrid catalyst were investigated using Fourier transform infrared spectroscopy, small angle X–ray powder diffraction, field emission scanning electron microscope, transmission electron microscope, nitrogen adsorption–desorption analyses, and atomic absorption spectroscopy. The stabilized Pd species inside the mesochannels provided good catalytic efficiency for the Suzuki–Miyaura coupling reactions in water. The activity of the designed catalysts retained for several consecutive recycle runs. The stability, recoverability, and reusability of the designed heterogeneous catalyst were also studied under various reaction conditions.
پژوهشگران محمد رضا شکوهی مهر (نفر ششم به بعد)، ژنگ چین آن (نفر ششم به بعد)، کینگ شان کونگ (نفر پنجم)، ویلسن لی (نفر چهارم)، پریا پناهی (نفر سوم)، صادق رستم نیا (نفر دوم)، عارفه احدی (نفر اول)