عنوان
|
Synthesis and characterization of a new polyoxovanadate for the one-pot three-component (A3) coupling of aldehydes, amines and alkynes
|
نوع پژوهش
|
مقاله چاپشده در مجلات علمی
|
کلیدواژهها
|
Polyoxovanadate Decavanadate Three-component (A3) Coupling
|
چکیده
|
Polyoxovanadate, (NH4)2[Zn(H2O)6]2[V10O28]∙4H2O was synthesized and characterized by the single crystal Xray analysis. (NH4)2[Zn(H2O)6]2[V10O28]∙4H2O was found to be an efficient catalyst for one-pot synthesis of propargylamines by three component (A3) coupling of aldehydes, amines and alkynes without any co-catalyst or activator under solvent-free condition. In the presence of this catalytic system both aromatic and aliphatic aldehydes and alkynes could react and so produce the corresponding propargylamines in good to excellent yields.
|
پژوهشگران
|
جان جانسزاک (نفر چهارم)، سید مرتضی فامیل فرنیا (نفر سوم)، مجتبی امینی (نفر دوم)، هادی نسل حاجیان (نفر اول)
|