مشخصات پژوهش

عنوان	Supramolecular architecture constructed from the hemidirected lead(II) complex with N'-(4-hydroxybenzylidene)isonicotinohydrazide
نوع پژوهش	مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها	Lead(II) Tetrel bonding Coordination polymer X-ray crystallography Hirshfeld surface analysis Topology
چکیده	In this work we have directed our attention to the N'-(4-hydroxybenzylidene)isonicotinohydrazide (HL) as a linker for the production of a Pb(II) extended structure. As a result, discrete homoleptic coordination compound [PbL2] with two deprotonated ligands L was isolated. All the covalent PbN/O bonds are collected on a half of hemisphere of the globe of the coordination sphere yielding a large gap in the coordination sphere of Pb(II). This enables a close approach of the amide nitrogen atom from an adjacent molecule with the formation of a tetrel bond of about 3.0 Å, yielding 1D polymeric chains. These chains are interlinked via intermolecular OH⋯N hydrogen bonds and CH⋯π interactions, yielding a 3D structure. Considering OH⋯N intermolecular hydrogen bonds, molecules of [PbL2] form a single helical structural unit of a hexagonal shape. These motifs are mutualy interpenetrated and the overall 3D network of [PbL2] belongs to a ThSi2 network. The Pb⋯N tetrel bonding interaction was stiduied in details using DFT.
پژوهشگران	دمیر سفین (نفر ششم به بعد)، آنتونیو فرانترو (نفر ششم به بعد)، اننیو زانگراندو (نفر پنجم)، آرونوا گوپتا (نفر چهارم)، فنگرویی کیو (نفر سوم)، قدرت محمودی (نفر دوم)، فرهاد اکبری افخمی (نفر اول)