مشخصات پژوهش

عنوان	Selective catalytic generation of hydrogen over covalent organic polymer supported Pd nanoparticles (COP-Pd)
نوع پژوهش	مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها	Covalent organic polymer Formic acid Hydrogen evolution Dehydrogenation Heterogeneous catalysis
چکیده	Formic acid (FA) has long been regarded as a cheap and non-toxic hydrogen storage material due to its effective production of hydrogen in mild conditions. Though the development of heterogeneous catalysts has received much progress, their catalytic activity remains insufficient. Here, a porous Triazine-based covalent organic polymer (TA-COP) was fabricated via the Schiffbase condensation reaction. Then, experimental studies on palladium nanoparticles supported on a nitrogen-rich TA-COP substrate are combined for FA dehydrogenation to selective production of CO2and H2under mild conditions. The Pd(0)@TA COP showed high catalytic activity (TOF up to 233 h −1 ) and high hydrogen selectivity for the dehydrogenation of FA at 328 K. Our study demonstrated that the synergistic effects between the nitrogen-rich TA-COP support and Pd nanoparticles play a critical role in the efficient catalytic dehydrogenation of formic acid. This work provides a feasible strategy to design high-performance COP-based heterogeneous catalysts for catalyzing formic acid dehydrogenation.
پژوهشگران	صادق رستم نیا (نفر ششم به بعد)، بهنام قلی پور (نفر پنجم)، مصطفی فرج زاده (نفر چهارم)، نازنین مختاری (نفر سوم)، محمد دیناری (نفر دوم)، نسرین نوروزی (نفر اول)