مشخصات پژوهش

صفحه نخست /Helical coordination complex ...
عنوان Helical coordination complex of Hg(ClO4)2 with bulky hydrazone derivative: A Möbius-like discrete metal chelate
نوع پژوهش مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها Coordination chemistryMercuryHydrazone derivativeX-ray crystallographySpodium bonds
چکیده In this work we have synthesized and characterized a new coordination compound [HgL(ClO4)2EtOH] (1), fabricated from a mixture of Hg(NO3)2 and NaClO4 with 1,2-diphenyl-1,2-bis((phenyl-(pyridin-2-yl)methylene)hydrazono)ethane (L). Single-crystal X-ray crystallography revealed the formation of a mononuclear heteroleptic discrete structure with one molecule [HgL(ClO4)2EtOH] in the asymmetric unit. The ligand L adopts a helical twist conformation. The Hg(II) cation is coordinated by four nitrogen atoms from L and by three oxygen atoms from two monocoordinated ClO4– anions and one ethanol molecule. The crystal structure of 1 is stabilized by the intermolecular O–H⋯O hydrogen bonds, and Cl–O⋯πPh and C–H⋯πPh interactions, yielding a supramolecular 3D framework. Moreover, the long Hg–N/O bonds have been analyzed in terms of coordination, semicoordination or spodium bonds using QTAIM and NCIplot index computational tools.
پژوهشگران دمیر سفین (نفر ششم به بعد)، آنتونیو فرانترو (نفر ششم به بعد)، جاناتان وایت (نفر پنجم)، سایکات ست (نفر چهارم)، امانول پریالا (نفر سوم)، قدرت محمودی (نفر دوم)، ولی علیزاده (نفر اول)