مشخصات پژوهش

عنوان	Ordered mesoporous SBA-15/PrSO3Pd and SBA-15/PrSO3PdNP as active, reusable and selective phosphine-free catalysts in C[BOND]X activation Heck coupling process
نوع پژوهش	مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها	SBA-15/PrSO3Pd;SBA-15/PrSO3PdNP;interface catalyst;Heck reaction
چکیده	The incorporation of sulfonate into mesoporous SBA-15 molecular sieves as ligands for palladium ions was used. Then SBA-15/PrSO3Pd and SBA-15/PrSO3PdNP were prepared and applied for the Heck arylation reaction of conjugate alkenes with aryl halides, to afford corresponding cross-coupling products under phosphine-free aerobic conditions with good to excellent yields. These supported palladium pre-catalysts could be separated easily from reaction products and reused several times, showing superiority over homogeneous catalysts for industrial and chemical applications. Copyright © 2015 John Wiley & Sons, Ltd.
پژوهشگران	تورج رحمانی (نفر دوم)، صادق رستم نیا (نفر اول)