عنوان
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Surfactant-Exfoliated Highly Dispersive Pd-Supported Graphene Oxide Nanocomposite as a Catalyst for Aerobic Aqueous Oxidations of Alcohols
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نوع پژوهش
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مقاله چاپشده در مجلات علمی
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کلیدواژهها
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alcohols · graphene · palladium · supported catalysts · surfactants
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چکیده
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A pluronic P123 surfactant was employed in the exfoliation and stabilization of Pd0-supported graphene oxide (PdNPs–GO; NPs=nanoparticles) nanosheets in aqueous solution during the oxidation of benzylic and aliphatic alcohols under aerobic conditions at 80 °C. Surfactants prevented the aggregation of PdNPs–GO sheets at 80 °C under aqueous conditions and PdNPs–GO/P123 adducts acted as a highly dispersive homogeneous-like catalyst. The catalytic performance of the nanocomposite material was remarkably improved, being highly stable and reusable in the aerobic oxidation of alcohols for at least nine runs.
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پژوهشگران
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رافائل لوکوئه (نفر پنجم)، ثریا امینی (نفر چهارم)، زیبا کریمی (نفر سوم)، اسماعیل دوستخواه (نفر دوم)، صادق رستم نیا (نفر اول)
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